Notes from atomic Structure test:
The following are points that you need to clarify in order
to improve your understanding and marks on this unit:
·
Copper has the electronic configuration of [Ar]
3d10 4s1 (remember also that Cr has a half filled d subshell)
·
Although the 4s orbital fills before the 3d. The
4s electrons are removed first.
·
The definition of RAM! The weighted average of
an atom relative to a 1/12 of carbon-12
·
The sequence in a mass spectrometer is: vaporization,
ionization, acceleration, deflection and detection
·
Acceleration is caused by a very high positive potential
difference
·
Deflection is caused by an electromagnet around
the main tube, causing the positive ions to move in a curved path
·
The amount of deflection depends on the mass to
charge ratio (m/z). The higher the mass and lower the charge the bigger the m/z
ratio and the less the deflection. The lower the m/z ratio, the smaller the
mass and or the bigger the charge, the greater the deflection
·
Big jumps in ionization energy relate to
breaking into the next quantum level. This value is much higher as its nearer
the nucleus and the quantum level is full
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