Freitag, 11. November 2011

Notes from Atomic Structure Test



Notes from atomic Structure test:

The following are points that you need to clarify in order to improve your understanding and marks on this unit:

·      Copper has the electronic configuration of [Ar] 3d10 4s1 (remember also that Cr has a half filled d subshell)
·      Although the 4s orbital fills before the 3d. The 4s electrons are removed first.
·      The definition of RAM! The weighted average of an atom relative to a 1/12 of carbon-12
·      The sequence in a mass spectrometer is: vaporization, ionization, acceleration, deflection and detection
·      Acceleration is caused by a very high positive potential difference
·      Deflection is caused by an electromagnet around the main tube, causing the positive ions to move in a curved path
·      The amount of deflection depends on the mass to charge ratio (m/z). The higher the mass and lower the charge the bigger the m/z ratio and the less the deflection. The lower the m/z ratio, the smaller the mass and or the bigger the charge, the greater the deflection
·      Big jumps in ionization energy relate to breaking into the next quantum level. This value is much higher as its nearer the nucleus and the quantum level is full

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